Chlorine
Cl₂Chlorine (Cl₂) is a yellow-green gas with a strong, suffocating odor detectable at very low concentrations (0.5 ppm). Chlorine is widely used for water and wastewater treatment, swimming pool sanitation, chemical manufacturing, and bleaching processes. While essential for public health through water disinfection, chlorine is highly toxic and was historically used as a chemical weapon. OSHA PEL is 1 ppm ceiling with IDLH at 10 ppm—one of the most stringent exposure limits. Chlorine attacks the respiratory system, causing pulmonary edema even at moderate exposures. Comprehensive detection and emergency response systems are required in water treatment plants, chemical storage areas, and any facility handling chlorine.
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Key Information
Essential safety and exposure information for Chlorine
Health Effects
- Severe respiratory irritation
- coughing
- chest tightness
- pulmonary edema. Can be fatal at high concentrations.
Common Sources
- Water treatment facilities
- swimming pools
- chemical manufacturing
- and cleaning products.
Exposure Limits
- OSHA PEL
- 1 ppm (C)
- NIOSH REL
- 0.5 ppm (C)
- ACGIH TLV
- 0.1 ppm (ST 0.4)
Regulatory Status
- OSHA PEL
- 1 ppm ceiling
- NIOSH REL
- 0.5 ppm ceiling
- IDLH
- 10 ppm
- ACGIH TLV
- 0.1 ppm TWA, 0.4 ppm STEL
- EPA
- Extremely Hazardous Substance
- DOT
- Class 2.3 Toxic Gas, UN1017
Detection Requirements
- Sensor Technology
- Electrochemical
- Detection Range
- 0-10 ppm (safety) or 0-50 ppm (leak detection)
- Response Time
- <30 seconds (T90)
- Calibration Frequency
- Quarterly to semi-annual
- Alarm Setpoints
- Low 0.5 ppm, High 1 ppm (OSHA ceiling)
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