Critical Environment Technologies
    A2L Refrigerants

    R-1234ze

    C₃H₂F₄

    R-1234ze (1,3,3,3-tetrafluoropropene, HFO-1234ze) is a hydrofluoroolefin refrigerant with ultra-low GWP of less than 1, used primarily in commercial and industrial applications. The trans isomer (R-1234ze(E)) is used in centrifugal chillers, heat pumps, and as a foam blowing agent. R-1234ze offers excellent thermodynamic properties for medium-pressure applications with minimal environmental impact. Classified as A2L (mildly flammable) with relatively low flammability, R-1234ze is also used as a component in refrigerant blends like R-448A. The refrigerant is particularly suitable for large commercial buildings, district cooling, and industrial process cooling where its low-GWP benefits can be maximized.

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    Key Information

    Essential safety and exposure information for R-1234ze

    Health Effects

    Low acute toxicity. A2L mildly flammable classification. Excellent environmental profile with GWP less than 1.

    Common Sources

    • Positive displacement chillers
    • scroll compressors
    • foam blowing

    Exposure Limits

    WEEL
    800 ppm (8-hr TWA)
    A2L flammable
    A2L flammable
    HFO refrigerant
    HFO refrigerant

    Regulatory Status

    EPA Classification
    HFO (non-ODS)
    ASHRAE Safety Group
    A2L (low toxicity, mildly flammable)
    GWP (AR5)
    <1
    ODP
    0
    LFL
    7.6% by volume (trans isomer)
    EPA SNAP
    Listed as acceptable for various applications

    Detection Requirements

    Sensor Technology
    Infrared (NDIR) or Semiconductor
    Detection Range
    0-2,000 ppm typical
    Response Time
    <30 seconds (T90)
    Calibration Frequency
    Semi-annual to annual
    A2L Classification
    LFL monitoring may be required